What is Reverse Osmosis (RO) Definition

Reverse osmosis (RO) is basially the reverse of the osmosis process. Scientists found that all that is required to reverse the process of osmosis is a suitable semipermeable membrane and applying a pressure to the concentrated salt solution above the applied and osmotic back-pressures, thereby forcing pure water through the semipermeable membrane. In other words, reverse osmosis is the process where water containing inorganic salts (minerals), suspended solids, soluble and insoluble organics, aquatic microorganisms, and dissolved gases (collectively called source water constituents or contaminants) is forced under pressure through a semipermeable membrane. Semipermeable refers to a membrane that selectively allows water to pass through it at much higher rate than the transfer rate of any constituents contained in the water. Learn more about pressure driven membranes here. If water of high salinity is separated from water of low salinity via a semipermeable membrane, a natural process of transfer of water will occur from the low-salinity side to the high-salinity side of the membrane until the salinity on both sides reaches the same concentration. This natural process of water transfer through a membrane driven by the salinity gradient occurs in every living cell; it is known as osmosis.

The hydraulic pressure applied on the membrane by the water during its transfer from the low-salinity side of the membrane to the high-salinity side is termed osmotic pressure. Osmotic pressure is a natural force similar to gravity and is proportional to the difference in concentration of total dissolved solids (TDS) on both sides of the membrane, the source water temperature, and the types of ions that form the TDS content of the source water. This pressure is independent of the type of membrane itself. In order to remove fresh (low-salinity) water from a high-salinity source water using membrane separation, the natural osmosis-driven movement of water must be reversed, i.e., the freshwater has to be transferred from the high-salinity side of the membrane to the low-salinity side. For this reversal of the natural direction of freshwater flow to occur, the high-salinity source water must be pressurized at a level higher than the naturally occurring osmotic pressure.

If the high-salinity source water is continuously pressurized at a level higher than the osmotic pressure and the pressure losses for water transfer through the membrane, a steady-state flow of freshwater from the high-salinity side of the membrane to the low-salinity side will occur, resulting in a process of salt rejection and accumulation on one side of the membrane and freshwater production on the other. This process of forced movement of water through a membrane in the opposite direction to the osmotic force driven by the salinity gradient is known as reverse osmosis (RO).

The rate of water transport through the membrane is several orders of magnitude higher than the rate of passage of salts. This significant difference between water and salt passage rates allows membrane systems to produce freshwater of very low mineral content. The applied feed water pressure counters the osmotic pressure and overcomes the pressure losses that occur when the water travels through the membrane, thereby keeping the freshwater on the low-salinity (permeate) side of the membrane until this water exits the membrane vessel.

Osmosis and Reverse Osmosis Process

The salts contained on the source water (influent) side of the membrane are retained and concentrated; they are ultimately evacuated from the membrane vessel for disposal. As a result, the RO process results in two streams—one of freshwater of low salinity (permeate) and one of feed source water of elevated salinity (concentrate, brine or retentate), as shown in the figure above. While semipermeable RO membranes reject all suspended solids, they are not an absolute barrier to dissolved solids (minerals and organics alike). Some passage of dissolved solids will accompany the passage of freshwater through the membrane. The rates of water and salt passage are the two key performance characteristics of Reverse Osmosis membranes.

Reverse Osmosis Process Drawing