What is a Functional Group
Molecular compounds owe their individual properties to functional group. These are combinations of atoms which may appear in various parts of the molecule. A list of major functional group listed below.
| Illustrative Example | Name of Functional Class | Functional Group |
| CH3CH2CH3 | Alkanes | C-C |
| CH3CH=CH2 | Alkenes | C=C |
| CH3CH/CH | Alkynes | C/C |
| CH3CH2CH2OH | Alcohols | C–OH |
 |
Aldehydes |  |
 |
Ketones |  |
 |
Acids |  |
| CH3CH2CH2NH2 | Amines | C-NH2 |
| CH3OCH2CH3 | Ethers | -C-O-C- |
| CH3CH2CH2Br | Halides | C-Br |
The difference in electronegativity of two bonding atoms determines if the bond will be polar or nonpolar (read about polarity). The bond between two identical atoms is always nonpolar, (for example: C-C, C=C, C=C; H-H, O=O, etc…). Bonds between atoms with electronegativities which are nearly the same are nonpolar (for example C-H). Bonds between atoms with electronegativities which are significantly different (commonly 0.9) are polar (for example, C-O, H-O, C=O, and N-H).
One molecule, especially a large complex molecule, may have more than one type of functional group. One specific functional group may be repeated several times.
A functional group may alter the properties of a compound such as melting point, boiling point, solid structure, and solubility. A functional group on an organic molecule also contribute to its hydrophobic and hydrophilic properties. Surfaces composed of nonpolar molecules will be hydrophobic. Surfaces composed of compounds containing polar bonds will be hydrophilic. You can also read about surface tension.
- Published in Water Chemistry, Water Treatment
What is Surface Tension
Surface tension is one of the properties of water that is created by the Hydrogen bond. Surface tension is the reason a water droplet can have different shapes on different surfaces. As we all noticed, when we fill a glass of water to the top, water level may actually be above the glass rim. The explanation for this occurrence is the high surface tension of water on a hydrophilic surface like glass due to hydrogen bond.
surface tension of water on plastic hydrophobic
surface tension of water droplet on hydrophilic glass
Hydrophobic and Hydrophilic Examples
On the other hand, a water droplet tends to form a sphere like shape on a hydrophobic surface like for example plastic. Therefore, a drop of water will tend to spread on a clean glass surface. To simply explain why this happens, we will analyse the phenomenon on a molecular level. In the example of plastic and since it is a nonpolar substance; water will tend form hydrogen bonds with itself. In the example of glass which is polar; water molecules will form hydrogen bonds with the silicon dioxide of the glass. And this is what makes water tend to spread on the glass surface; attraction to glass. Read more about polarity.
Another example explaining surface tension, using a small glass tube called a capillary tube. If we place the end tip of this tube in a glass of water, water will drawn. This is because of the hydrogen bond occurring between the SiO2 of the glass tube and the Oxygen atoms in the water molecules. The definition of hydrophilic which is what describes the glass in this situation means water loving. While definition for Hydrophobic which is plastic in the above example means water hating.
surface tension capillary tube example water glass hydrophilic
A unit of measurement for the surface tension of water is dynes/cm at room temperature. Which is the force you have to overcome in order to break the surface tension of a water droplet (1cm in length). The lower the temperature the less surface tension. Hot water makes a better cleaning solution since it is considered a better wetting agent. This is due to low surface tension of hot water which allows it to better react with detergents which are hydrocarbons with a polar end called a functional group.
- Published in Water Chemistry, Water Treatment
